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投稿时间:2024-03-31 修订日期:2024-04-23
投稿时间:2024-03-31 修订日期:2024-04-23
中文摘要: 目的:了解典型喀斯特地区尾矿库周边植物的重金属富集特性和空间分布特征,筛选优势植物品种。方法:计算富集系数来判断不同植物对不同重金属的富集能力;采用地理信息分析软件(GIS)通过普通克里金插值和半变异函数分析,建立植物重金属空间分布模型;计算皮尔逊相关系数,以分析植物体内各重金属之间及与土壤pH值的相关性。结果:该尾矿库周边28种植物中,茄科植物红丝线、菊科的野茼蒿和荨麻科的八角麻对Cd有较强富集能力,植物中Cd污染严重;乌毛蕨科的苏铁蕨、海金沙科的小叶海金沙和大戟科的禾串树对Pb有较强富集能力;各植物对Cu和Zn均无富集作用。重金属空间分布模型显示,Cd主要分布在尾矿库南面、西南面、东南面和西北面;Pb主要分布在东南部、坝下小溪及正南面;Cu主要分布在正南、西南和坝下小溪方向;Zn主要分布在西面、西南、西北和正北面。在半变异函数模型参数中,Cd和Zn以随机性因素误差为主,各点的空间相关性弱,Pb、Cu以结构性因素误差为主,空间相关性较强;植物体内重金属含量空间变异性和空间相关性排序为Zn<Cd<Cu<Pb。Cd与Cu存在中等程度正相关关系,Cd与Pb、Zn呈正弱相关关系;植物体内各重金属含量与土壤pH值相关性不强。结论:筛选出的部分优势植物可作为矿区土壤重金属富集转移和生物修复的备选品种,初步了解了该区域重金属在土壤和植物之间的迁移规律,为开展矿区重金属污染治理提供了依据。
Abstract:Purpose: To investigate the heavy metal enrichment and spatial distribution characteristics of plants around tailings ponds in typical karst areas, and to screen the dominant plant varieties. Methods: The enrichment coefficient was calculated to determine the enrichment ability of different plants to different heavy metals. The spatial distribution model of plant heavy metals was established utilizing general Kriging interpolation and semi-variance function analysis using geographic information analysis software (GIS). The Pearson correlation coefficient was calculated to analyze the correlation between various heavy metals in plants and soil pH value. Results: Among the 28 plants around the tailings pond, Peristrophe roxburghiana of Solanaceae, Gynura crepidioides of Compositae, and Boehmeria tricuspis of Nettle family had strong enrichment ability of Cd, and Cd pollution was serious in plants. Lyginodendron oldhamium Potonie of Blechnaceae, Bridelia insulana of Euphorbiaceae had strong enrichment capacity for Pb. There was no enrichment of Cu and Zn in all plants. The spatial distribution model of heavy metals showed that Cd was mainly distributed in the south, southwest, southeast and northwest parts of the tailings pond. Pb is mainly distributed in the southeast, the stream under the dam, and the south. Cu was mainly distributed in the south, southwest and the stream direction under the dam. Zn is mainly distributed in the west, southwest, northwest and north. In the semi-variance model parameters, Cd and Zn were dominated by random errors, and the spatial correlation of each point was weak, while Pb and Cu were dominated by structural errors, and the spatial correlation was strong. The spatial variability and correlation of heavy metal content in plants were Zn < Cd < Cu < Pb. There was a moderately positive correlation between Cd and Cu, and a weakly positive correlation between Cd and Pb and Zn. There was no strong correlation between the contents of heavy metals in plants and soil pH value. Conclusion: Some of the selected dominant plants could be used as alternative varieties for heavy metal accumulation and transfer in soil and bioreactor, and the migration law of heavy metals between soil and plants in this area was preliminaries understood, which provided a basis for carrying out heavy metal pollution control in the mining area.
keywords: karst region lead-zinc tailings pond plant heavy metal enrichment spatial distribution characteristics enrichment factor
文章编号: 中图分类号:X53?? 文献标志码:
基金项目:广西自然科学基金项目(2013GXNSFAA019289);河池学院硕士专业学位建设基金课题(2017HJA002);河池学院高层次人才科研启动费项目(2019GCC007)
作者 | 单位 | |
韦岩松 | 微生物及植物资源开发利用广西高校重点实验室 | weiyans@126.com |
农韦杰 | 微生物及植物资源开发利用广西高校重点实验室 | |
郑华明 | 微生物及植物资源开发利用广西高校重点实验室 | |
李秀玲* | 微生物及植物资源开发利用广西高校重点实验室 | 275834674@qq.com |
引用文本:
韦岩松,农韦杰,郑华明,李秀玲.喀斯特地区尾矿库周边植物重金属富集特征及空间分布[J].有色金属(矿山部分),2024,76(4):133-141.
WEI Yansong,NONG Weijie,ZHENG Huaming,LI Xiuling.Enrichment characteristics and spatial distribution of heavy metals in plants around tailing ponds in karst area[J].NONFERROUS METALS(Mining Section),2024,76(4):133-141.
韦岩松,农韦杰,郑华明,李秀玲.喀斯特地区尾矿库周边植物重金属富集特征及空间分布[J].有色金属(矿山部分),2024,76(4):133-141.
WEI Yansong,NONG Weijie,ZHENG Huaming,LI Xiuling.Enrichment characteristics and spatial distribution of heavy metals in plants around tailing ponds in karst area[J].NONFERROUS METALS(Mining Section),2024,76(4):133-141.