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有色金属(矿山部分):2024,76(5):185-192
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矿冶固废制备混凝土配合比优化及耐久性研究
杨艳会1,郑 明1,袁 胜1,张广田2,3,于海洋2,3,张立群1
((1. 国网河北省电力有限公司建设公司,石家庄 050000;2. 河北省建筑科学研究院有限公司,石家庄 050000;3. 河北省固废建材化利用科学与技术重点实验室,石家庄 050000))
Study on Mix Proportion Optimization and Durability of Concrete Prepared from Mining and Metallurgical Solid Waste
YANG Yanhui1,ZHENG Ming1,YUAN Sheng1,ZHANG Guangtian2,3,YU Haiyang2,3,ZHANG Liqun1
((1 State Grid Hebei Electric Power Engineering Co., Ltd., Shijiazhuang 050000, China; 2 Hebei Academy of Building Research Co.,Ltd., Shijiazhuang 050000, China; 3 Key Laboratory of Science and Technology of Solid Waste Building Materials Utilization in Hebei Province., Shijiazhuang 050021, China))
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本文已被:浏览 950次   下载 1278
投稿时间:2024-03-18    修订日期:2024-05-20
中文摘要: 目的:为解决工业固废大量堆存、占用土地造成的环境污染问题,提高工业固废综合利用效率。方法:以钢渣、矿渣、脱硫石膏等工业固废为原材料制备的固废基胶凝材料,与水泥、粉煤灰按照不同比例混合,再以铁尾矿砂、铁尾矿碎石为骨料,制备C30强度等级的低碳混凝土,试验研究了水泥取代率、粉煤灰掺量对低碳混凝土抗压强度的影响,分析了全固废低碳混凝土的耐久性能,并通过XRD、TG-DSC、SEM的手段探究了固废基胶凝材料的水化产物及过程。结果:结果表明:在粉煤灰掺量80 kg/m3的条件下,固废基胶凝材料对水泥的取代率可达50%~70%,固废基胶凝材料完全取代水泥时宜作为单一胶凝材料使用;全固废低碳混凝土具有良好的耐久性能,其抗氯离子渗透性能、抗冻性能均优于普通混凝土。结论:固废基胶凝材料的早期水化进程较慢,其强度发展依赖于AFt和C-S-H凝胶的大量生成,二者相互交织、穿插提高了胶凝体系的密实度和强度。意义与创新性:本文论证了工业固废制备低碳混凝土的可行性,对混凝土绿色低碳发展具有实际指导意义。
Abstract:Purpose: In order to solve the environmental pollution problem caused by the large amount of industrial solid waste stockpiling and land occupation, and to improve the comprehensive utilization efficiency of industrial solid waste. Method: we prepared low-carbon concrete with C30 strength grade, which is prepared by mixing solid waste-based cementitious materials with cement and fly ash in different proportions, and then using iron tailing sand and iron tailing gravel as aggregates. Among them, solid waste-based cementitious materials consist of typical process solid wastes such as steel slag, slag, and desulfurization gypsum. The experiments investigated the effects of cement substitution rate and fly ash admixture on the compressive strength of low-carbon concrete, analyzed the durability performance of all-solid-waste low-carbon concrete, and explored the hydration products and processes of solid-waste-based cementitious materials using XRD, TG-DSC, and SEM. Result: The results show that: under the condition of 80 kg/m3 of fly ash mixing, the replacement rate of cement by solid waste-based cementitious materials could reach 50%~70%, and it was appropriate to use solid waste-based cementitious materials as a single cementitious material when they completely replace cement. The all-solid-waste low-carbon concrete had good durability performance, and its anti-chlorine ion penetration performance and frost resistance were better than that of ordinary concrete. Conclusion: The early hydration process of solid waste-based cementitious materials was slow, and their strength development relied on the massive generation of AFt and C-S-H gels, which were intertwined and interspersed with each other to improve the compactness and strength of the cementitious system. Significance: This paper demonstrates the feasibility of preparing low-carbon concrete from industrial solid waste, which has practical significance in guiding the green and low-carbon development of concrete.
文章编号:     中图分类号:TU528    文献标志码:
基金项目:国家电网公司科学技术项目(SGHEJS00YJJS2310202)
引用文本:
杨艳会,郑 明,袁 胜,张广田,于海洋,张立群.矿冶固废制备混凝土配合比优化及耐久性研究[J].有色金属(矿山部分),2024,76(5):185-192.
YANG Yanhui,ZHENG Ming,YUAN Sheng,ZHANG Guangtian,YU Haiyang,ZHANG Liqun.Study on Mix Proportion Optimization and Durability of Concrete Prepared from Mining and Metallurgical Solid Waste[J].NONFERROUS METALS(Mining Section),2024,76(5):185-192.

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