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有色金属(矿山部分):2015,67(5):-
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广西金牙金矿载金硫化物化学成分特征及其对成矿物源的指示
李院强,庞保成,吕嘉文,刘奕志,李培荣,周业泉,蒋新红,刘旭
(桂林理工大学 地球科学学院;桂林理工大学 广西隐伏金属矿产勘查重点实验室,桂林理工大学 地球科学学院;桂林理工大学 广西隐伏金属矿产勘查重点实验室,桂林理工大学 地球科学学院,桂林理工大学 地球科学学院;桂林理工大学 广西隐伏金属矿产勘查重点实验室,桂林理工大学 地球科学学院,桂林理工大学 地球科学学院,桂林理工大学 地球科学学院,桂林理工大学 地球科学学院)
Composition of Gold-bearing Sulfides and Their Implication for Ore-Forming Materials in Jinya Gold Deposit, Guangxi, China
LI Yuan-qiang,PANG Bao-cheng,LV Jia-wen,Liu Yi-zhi,LI Pei-rong,ZHOU Ye-quan,JIANG Xin-hong and LIU Xu
(College of Earth Sciences,Guilin University of Technology,Guilin;China;Guangxi Key Laboratory of Hidden Metallic Ore Deposit Exploration,Guilin University of Technology,Guilin;China,College of Earth Sciences,Guilin University of Technology,Guilin,College of Earth Sciences,Guilin University of Technology,Guilin,College of Earth Sciences,Guilin University of Technology,Guilin,College of Earth Sciences,Guilin University of Technology,Guilin,College of Earth Sciences,Guilin University of Technology,Guilin,College of Earth Sciences,Guilin University of Technology,Guilin,College of Earth Sciences,Guilin University of Technology,Guilin)
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投稿时间:2015-07-22    修订日期:2015-07-22
中文摘要: 金牙金矿是桂西北地区最早发现、也是国内较典型的卡林型金矿之一,矿体受桂西-百色断褶带北东侧近南北向次级断裂控制,赋存于三叠纪百逢组细砂-粉砂岩、泥质粉砂岩中。地质、岩相学和载金硫化物电子探针分析研究表明,金牙金矿至少发育两个阶段的热液矿物组合,多数矿物具有多世代的特征。黄铁矿和毒砂中As与S呈负相关关系,Au与As相关关系不明显。不同阶段的黄铁矿Au、As表现出一定的规律,黄铁矿沉积期Au、As总体较低,成岩期Au、As明显升高;成矿期各阶段热液黄铁矿均含有较高Au、As,其包裹的交代残余黄铁矿中Au、As变化较大,可能受后期热液作用使Au、As发生了活化迁移。Co、Ni分析表明矿石中黄铁矿主要为热液成因,围岩中黄铁矿主要为沉积成因,蚀变围岩中黄铁矿两种成因兼有;环带状黄铁矿核部(Py2?)既有沉积成因又有热液成因特征,可能由于沉积成岩期的沉积成因型黄铁矿受后期热液作用叠加改造发生改变的结果。Py2?中的Au、As含量均低于中部和边部,推断认为可能是由于沉积-成岩阶段的黄铁矿在后期构造或热液作用过程中,其Au、As被熔解并搬运、迁移,使核部表现出Au、As含量降低的现象。沉积-成岩阶段的黄铁矿和毒砂均含Au,且成矿热液的S来自其流经地层中的S,推断成矿物质可能主要来源于三叠纪百逢组地层。根据对该地区分析和前人研究结果,不排除有含Au质岩浆沿深大断裂上升迁移贡献金源的可能性。据以上事实推断成矿作用可分为三个阶段:沉积成岩期Au预富集→成矿期萃取先期富集成矿物质形成含矿流体上升迁移,在有利的场所卸载成矿并使围岩矿化蚀变→成矿期后受风化和淋滤作用形成氧化矿石。
Abstract:The Jinya gold deposit is a typical Carlin-type gold deposit, and it is one of the first discovered Carlin-type gold deposits in China. The gold deposit is mainly hosted in the Middle Triassic fine-sandstones, siltstone, argillacoue siltstone. The deposit is obviously controlled by the NS-trending secondary fault in the northeast of NE-trending Guixi-Baise fault. Field work, petrography, electron microprobe date indicate that hydrothermal minerals in Jinya gold deposit could be classified into at least two forming stages. Most of these minerals have characteristic of multiple generations. There is a negative correlation between As and S content in the pyrites and arsenopyrite. The correlation between As and Au is no obvious. Au and As contents in the pyrite formed in different stage have regular patterns. The contents of Au and As in the sedimentary pyrite are low. In contrary, these contents in the diagenesis pyrite are much higher. Hydrothermal pyrite developed in every stage of ore-forming period has abundant Au and As. The varing contents of Au and As in the relict pyrites in the core of banded pyrite which indicate that some Au and As have been activated and migrated in some test area during the later hydrothermal activity. Analysis of Co and Ni in pyrite suggest that the pyrites in ore bodies are hydrothermal pyrite, the pyrites in adjacent rocks are sedimentary pyrite, the pyrites in alteration wall-rock comprising both of them. The pyrite(Py2?) with the characteristics of hydrothermal pyrite and sedimentary pyrite in the ore of banded pyrite probably due to the pyrites in the stage of sedimengtary and diagenesis derived from hydrothermal-superimposing in later hydrothermal activity. Its Au and As contents are less than the other parts. It is possibly show that Au and As in the sedimentary pyrite resolved and migrated during the later hydrothermal activity. That caused the lower content of Au and As in the core of the pyrite. The pyrite and arsenopyrite in the diagenesis contained some Au, and S of the ore fluid derived from the strata that it flows through, which suggests the ore-forming material major derived from the country rocks. However, according to the previous analysis, there may be igneous rocks containing Au rise and migration along the deep fracture. Based on the above data, the mineralization may be divided into three stages: The Au pre-enrichment in the diagenetic stage→The fulid of the mineralization period extracted the ore-forming material which pre-enriched in the first stage, and it rose and migrated along the deep fault and fracture zone. The ore bearing fluid unloads in syn-sedimentary faults, econdary fault and favorable lithology sites, and made the wall rock altered→After the metallogenic epoch, the ore bodies form the oxidized ore by weathering and leaching under acidic conditions.
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基金项目:国家自然科学基金(41362006),广西自然科学基金(2013GXNSFAA019275)
引用文本:
李院强,庞保成,吕嘉文,刘奕志,李培荣,周业泉,蒋新红,刘旭.广西金牙金矿载金硫化物化学成分特征及其对成矿物源的指示[J].有色金属(矿山部分),2015,67(5):.
LI Yuan-qiang,PANG Bao-cheng,LV Jia-wen,Liu Yi-zhi,LI Pei-rong,ZHOU Ye-quan,JIANG Xin-hong,LIU Xu.Composition of Gold-bearing Sulfides and Their Implication for Ore-Forming Materials in Jinya Gold Deposit, Guangxi, China[J].NONFERROUS METALS(Mining Section),2015,67(5):.

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