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投稿时间:2013-10-28 修订日期:2013-10-31
投稿时间:2013-10-28 修订日期:2013-10-31
中文摘要: 本文以721铀矿山云际矿石为研究对象,通过室内铀矿石柱浸试验,研究铀矿石在细菌池浸过程中钍浸出特征。研究结果表明,柱浸过程中,水文地球化学条件(pH和Eh)对钍浸出影响不大,随着时间变化,pH值在1.73到1.36之间发生变化,Eh值在169mV到592mV之间变化,但Th浸出量基本稳定在2.2 mg/L与2.5 mg/L之间。同时实验表明,原矿铀浸出率为80.03%,Th的浸出率仅约为14.1%,主要原因U、Th的化学性质不同,Th均以 4价稳定存在于矿石中,一般不易被溶解而迁移转化。U具有多种价态,在氧化条件下显 6价,而这种价态的U性质活泼,易于在环境中迁移转化。
Abstract:In this paper, the Cloud occasion ore of 721 uranium mines was selected to study the characteristics of thorium leaching in the process of uranium mines bacteria tank leaching .The results indicated that hydrogeochemical conditions(pH and Eh) have little effect on the leaching of thorium in the process of column leaching, over time, pH values changed between 1.73 to1.36, Eh values changed between 169mV to 592mV, but the amount of Th leaching stable at 2.2 mg / L to 2.5 mg / L .At the same time,during the experiment, the leaching rate of uranium is 80.03%, the leaching rate of Th is just 14.1%,mainly because of the different chemical properties between U and Th.Th is difficult to be dissolved,migration and transformation because Th is present in the ore with the stability form 4 price.U has multiple valence states,it is easy to transport and transformation in the environment,because U is present in the ore with the lively form 6 price.
keywords: column leaching the amount of U leaching the amount of Th leaching
文章编号: 中图分类号: 文献标志码:
基金项目:国家自然科学基金项目(面上项目,重点项目,重大项目)
作者 | 单位 | |
汪勇 | 东华理工大学 | 872305003@qq.com |
陈建 | 核工业华东建设工程集团 | |
高柏* | 东华理工大学 | anhuiwangyong1001@qq.com |
周敏 | 东华理工大学 | |
杜洋 | 东华理工大学 | |
占凌之 | 东华理工大学 |
引用文本:
汪勇,陈建,高柏,周敏,杜洋,占凌之.细菌柱浸铀矿工艺过程中钍浸出特征实验研究[J].有色金属(矿山部分),2014,66(2):.
Wang Yong,Chen Jian,Gao Bai,Zhou Min,Du Yang,Zhuan Lingzhi.The characteristic experimental study on the thorium leaching in the process of bacteria column leaching of Uranium leaching[J].NONFERROUS METALS(Mining Section),2014,66(2):.
汪勇,陈建,高柏,周敏,杜洋,占凌之.细菌柱浸铀矿工艺过程中钍浸出特征实验研究[J].有色金属(矿山部分),2014,66(2):.
Wang Yong,Chen Jian,Gao Bai,Zhou Min,Du Yang,Zhuan Lingzhi.The characteristic experimental study on the thorium leaching in the process of bacteria column leaching of Uranium leaching[J].NONFERROUS METALS(Mining Section),2014,66(2):.